Sodium samarium tetrakis(polyphosphate), NaSm(PO3)4

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Sodium samarium tetra­kis­(poly­phosphate), NaSm(PO3)4

NaSm(PO(3))(4) has been prepared by solid state reactions. It belongs to type II of the structural family of M(I)Ln(III)(PO(3))(4) compounds (M(I) = alkali metal and Ln(III) = rare earth metal) and is composed of (∞)(PO(3))(n)](n-) polyphosphate chains with a repeating unit of four PO(4) tetra-hedra. The chains extend parallel to [100] and share O atoms with irregular SmO(8) polyhedra, forming ...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s1600536810022543